Ohhh this is tough.
Not from a super technical point of view or anything but for fitting the course and explaning the right feeling...
Lady Picture Show would probably be my pick. Again, not really anything that shows itself off in the guitar world, but I think it shines insanely bright and it’s just the right touch. I love how on the live version at spring break 97, the solo just sounds so good as dean drops immediately back into the riff. That particular performance showed me the sonic brilliance of this solo.
Second mention will be my all time favorite song big empty. Again not super technical, but that vibe!!!